Analytical Methods for H in Minerals
Updated 3-Jul-2023 by GR Rossman
1950s
- Bigeleisen K, Perlman ML, Prosse HC (1952) Conversion of
Hydrogenic Materials to Hydrogen for Isotopic Analysis. Analytical
Chemistry 24, 1356-1357.
- Nakamoto K, Margoshes M, Rujndle RE (1955) Stretching Frequencies
as a Function of Distances in Hydrogen Bonds. Journal of the American
Chemical Society 77, 6480-6486.
1960s
- Bellamy LJ, Owen AJ (1969) A simple relationship between the
infra-red stretching frequencies and the hydrogen bond distances in
crystals. Spectrochimica Acta, Part A (Molecular Spectroscopy) 25A,
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1970s
- Leich DA, Tombrello TA (1973) A technique for measuring hydrogen
concentrations versus depth in solid samples. Nuclear Instruments and
Methods 108, 67-71.
- Hinthorne JR, Andersen CA (1975) Microanalysis for fluorine and
hydrogen in silicates with the ion microprobe mass analyzer. American
Mineralogist 60, 143-147.
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precision technique for measiuring the concentration versus depth of
hydrogen in solids. Applied Physics Letters 28, 566-568.
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hydrogen in silicates using the ion beam spectrochemical analyzer:
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1980s
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concentration in silicates using ion-beam spectrochemical analysis
(IBSCA). Physics and Chemistry of Minerals 5, 315-326.
- Moze O, Hicks TJ, McLaren, AC (1980) Determination of the
hydrogen content of synthetic quartz by neutron polarization analysis.
Physics and Chemistry of Minerals, 5(4), 309-14.
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- Aines RD, Rossman GR (1984) The hydrous component in garnets.
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correlation of O-D(H)...Y (Y=N,O,S,Se,Cl,Br, I) hydrogen bonds in solid
dydrates. Journal of Molecular Structure 147, 1-15.
- Xiong F, Rauch F, Shi C, Zhou Z, Livi RP, Tombrello TA (1987)
Hydrogen depth profiling in solids: a comparison of several resonant
nuclear reaction techniques. Nuclear Instruments and Methods in Physics
Research B27, 432-441.
- Rossman GR, Rauch F, Livi R, Tombrello TA, Shi CR, Zhou ZY (1988)
Nuclear analysis of hydrogen in almandine, pyrope, and spessartite
garnets. Neues Jahrbuch für Mineralogie, Monatshefte 1988,
172-178.
- Yesinowski JP, Eckert H, Rossman GR (1988) High-speed proton
MAS-NMR of minerals. Journal of the American Chemical Society 110,
1367-1375.
- Yurimoto H, Kurosawa M, Sueno S (1989) Hydrogen
analysis in quartz crystals and quartz glasses by secondary ion mass
spectrometry. Geochimica et Cosmochimica Acta 53:751-755.
1990s
- Rossman GR (1990) Hydrogen in "anhydrous" minerals. Nuclear
Instruments and Methods in Research B45, 41-44.
- Kurosawa M, Yurimoto H, Matsumoto K, Sueno S (1992) Hydrogen
analysis of
mantle olivine by secondary ion mass spectrometry. In: Syono, Manghnani
MH (eds) High-Pressure Research in Mineral Physics: Application to
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Tokyo/Washington DC.
- Kurosawa M, Yurimoto H, Matsumoto K, Sueno S (1992) Quantitative
analysis of H, Ca and Ni in olivine by secondary ion mass spectrometry.
Annual Report of the Institute of Geosciences University of Tsukuba 18,
83–89.
- Fujimoto K, Fukutani K, Tsunoda M, Yamashita H, Kobayashi K
(1993) Hydrogen depth profiling using 1H(15N,alpha-gamma)12C
resonant nuclear reaction on water-treated olivine surfaces and
characterization of hydrogen species. Geochemical Journal
27, 155-162.
- Bell
DR,
Ihinger PD, Rossman GR (1995) Quantitative analysis
of hydroxyl in garnet and pyroxene. American Mineralogist 80,
465-474.
- Sie SH, Suter GF, Chekhmir A, Green TH (1995)
Microbeam recoil detection for the study of hydration of minerals.
Nuclear Instruments and Methods in Physics Research Section B: Beam
Interactions with Materials and Atoms 104, 261-265.
- Libowitzky E, Rossman GR (1996) Principles of quantitative
absorbance measurements in anisotropic crystals. Physics and
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- Mikenda
W, Steinböck S (1996) Stretching frequency vs. bond distance
correlation of hydrogen bonds in solid hydrates: a generalized
correlation function. Jourmal of Molecular Structure 384, 159–163.
- Sweeney RJ, Prozesky VM, Springhorn KA (1997) Use of the elastic
recoil detection analysis (ERDA) microbeam technique for the
quantitative determination of hydrogen in materials and hydrogen
partitioning between olivine and melt at high pressures -
Geochimica et Cosmochimica Acta 61, 101-113.
- Libowitzky E, Rossman GR (1997) An IR absorption calibration for
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- Nakashima Y, Nakashima S, Gross D, Weiss K, Yamauchi K (1998) NMR
imaging of 1H in hydrous minerals. Geothermics 27, 43-53.
- Libowitzky E (1999) Correlation of O-H Stretching Frequencies and
O-H···O Hydrogen Bond Lengths in Minerals. Monatshefte für Chemie 130,
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2000-2004
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minerals measured by FTIR and 1H MAS NMR: the effect
of sample preparation. Physics and Chemistry of Minerals 27.
371-376.
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Husler J, Leeman W, McGuire AV, Rhede D, Rothe H, Paul RL, Richards I,
Yates M (2001) Reference Minera ls for the Microa na lysis of Light
Elements. The Journal of Geostandards and Geoanalysis 25, 451-463.
- Eiler JM, Kitchen N (2001) Hydrogen-isotope analysis of nanomole
(picoliter) quantities of H2O. Geochimica et Cosmochimica Acta 65,
4467– 4479.
- Furuno K, Komatsubara T, Sasa K, Oshima H, Yamato Y, Ishii S,
Kimura H, Kurosawa M (2003) Measurement of hydrogen concentration in
thick
mineral or rack samples. Nuclear Instruments and Methods in Physics
Research B 210, 459-463.
- Koga K, Hauri E, Hirschmann
M, Bell D (2003) Hydrogen concentration analyses using SIMS and FTIR:
Comparison and calibration for nominally anhydrous minerals.
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H, Ishii S, Komatsubara T, Kurosawa M (2003) The Tsukuba
high-energy nuclear microprobe for hydrogen analysis of mineral
samples. Nuclear Instruments and Methods in Physics Research
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coefficients between nominally anhydrous minerals and basaltic melts.
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Schilling F, Lauterjung J (2004) The influence of OH in coesite on the
kinetics of the coesite-quartz phase transition. American Mineralogist
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534-549.
- Wegdén M, Kristiansson P, Pastuovic Z, Skogby H, Auzelyte V,
Elfman M, Malmqvist KG, Nilsson C, Pallon J, Shariff A (2004) Hydrogen
analysis by p–p scattering in geological material. Nuclear
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2005-2009
- Wegden M, Kristiansson P, Skogby H, Auzelyte V, Elfman M,
Malmqvist KG, Nilsson C, Pallon J, Shariff A (2005) Hydrogen depth
profiling by p–p scattering in nominally anhydrous minerals. Nuclear
Instruments and Methods in Physics Research B 231, 524–529.
- Asimow PD, Stein LC, Mosenfelder JL, Rossman GR (2006)
Quantitative
polarized FTIR analysis of trace OH in populations of randomly oriented
mineral grains. American Mineralogist 91, 278-284.
- Kohn
SC (2006) Structural studies of OH in nominally anhdyrous minerals
using NMR. Reviews in Mineralogy and Geochemistry 62, 53-66.
- Libowitzky E, Beran A (2006) The structure of hydrous species in
nominally anhydrous minerals: information from polarized IR
spectroscopy. Reviews in Mineralalogy and Geochemistry 62, 29-52.
- Rossman
GR (2006) Analytical methods for measuring water in nominally anhydrous
minerals. In: Keppler H and Smyth JR, eds, Water in Nominally Anhydrous
Minerals. Reviews in Mineralogy and Geochemistry 62, 1-28.
- Aubaud C, Withers AC, Hirschmann MM, Guan Y, Leshin LA, Mackwell
SJ,
Bell DR (2007) Intercalibration of FTIR and SIMS for hydrogen
measurements
in glasses andnominally anhydrous minerals. American Mineralogist
92, 811–828.
- Ludwig T, Stalder R (2007) A new method to eliminate the
influence of in situ contamination in SIMS analysis of
hydrogen. Journal of Analytical Atomic Spectroscopy 22,
1415-1419
- O'Leary JA, Rossman GR, Eiler J (2007) Hydrogen analysis in
minerals by continuous-flow mass spectrometry. American Mineralogist
92, 1990-1997.
- Wegden M, Kristiansson P, Skogby H, Auzelyte V, Elfman M,
Malmqvist KG, Nilsson C, Pallon J, Shariff A (2005) Hydrogen depth
profiling by p–p scattering in nominally anhydrous minerals. Nuclear
Instruments and Methods in Physics Research B 231, 524–529.
- Kovacs I, Hermann J, O'Neill HSC, Gerald JF,
Sambridge M, Horvath G (2008) Quantitative absorbance spectroscopy with
unpolarized light: Part II. Experimental evaluation and development of
a protocol for quantitative analysis of mineral IR spectra. American
Mineralogist 93, 765–778.
- Sambridge M, Gerald JF, Kovacs K, O'Neill HSC, Hermann J
(2008) Quantitative absorbance spectroscopy with unpolarized light:
Part I. Physical and mathematical development. American Mineralogis 93,
751–764.
- Bureau H, Raepsaet C, Khodja H, Carraro A, Aubaud C (2007)
Determination of hydrogen content in geological samples using elastic
recoil detection analysis (ERDA). Geochimica et Cosmochimica Acta 73,
3311–3322.
- Xue X, Kamzaki M (2009) H Proton
Distributions and Hydrogen Bonding in Crystalline and Glassy Hydrous
Silicates and Related Inorganic Materials: Insights from
High-Resolution Solid-State Nuclear Magnetic Resonance Spectroscopy.
Journal of the American Ceramic Society 92, 2803-2830.
2010s
- Prechtel F, Stalder R (2010) FTIR spectroscopy with a focal
plane
array detector: A novel tool to monitor the spatial OH-defect
distribution in single crystals applied to synthetic enstatite.
American Mineralogist 95, 888–891.
- Withers AC (2013) On the use of unpolarized infrared spectroscopy
for quantitative analysis of absorbing species in birefringent
crystals. American Mineralogist 98, 689-697.
- Stephant A, Remusat L, Thomen A, Robert F (2014) Reduction of OH
contamination in quantification of water contents using NanoSIMS
imaging. Chemical Geology 380, 20-26.
- Withers A, Mosenfelder J, Bureau H, Raepsaet C, Hirchmann M
(2014) Analysis of
H in Natural and Experimental Nominally Anhydrous Minerals: A
Comparison of Elastic Recoil Detection Analysis, Infrared and SIMS
Measurements. AGU ERDA abstract V41A-4764.
- Kumamoto KM,
Warren JM, Hauri EH (2017) New SIMS reference materials for measuring
water in upper mantle minerals. American Mineralogist
102, 537-547.
- Shuai
K, Yang X (2017) Quantitative analysis of H-species in anisotropic
minerals by polarized infrared spectroscopy along three
orthogonal directions. Contributions to Mineralogy and
Petrology 172, 14.
- Jackson
A, Parker RL, Sambridge M, Constable C, Wolf AS (2018) The inverse
problem of unpolarized infrared spectroscopy of geological materials:
Estimation from noisy random sampling of a quadratic form. American
Mineralogist 103, 1176–1184.
- Qiu
Y, Jiang H, Kovacs I, Xia QK, Yang X (2018) Quantitative analysis of
H-species in anisotropic minerals by unpolarized infrared spectroscopy:
An experimental evaluation. American Mineralogist 103, 1761–1769.
- Weis FZ, Ros L, Reichart P,
SKogby H, Kristlansson P, Dollinger G (2008) Hydrogen concentration
analysis in clinopyroxene usingproton–proton scattering analysis.
Physics and Chemistry of Minerals 45, 669-678.
- Zhang WF, Xia XP, Eiichi T, Li L, Yang Q, Zhang YQ,
Yang YN, Liu ML, Lai C (2019) Optimization of SIMS analytical
parameters for water content measurement of olivine. Surface and
Interface A,alysis 52, 224-233.