H in Rutile
Updated 10-Feb-2024 by GR Rossman
1960s
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OW, DeFord J, Shaner JW (1973) Experimental technique for the
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1980s
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1990s
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V (1990) IR spectroscopic and chemical study of a rutile from
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GR, Smyth JR (1990) Hydroxyl contents of accessory minerals in mantle
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R, Smyth J, Larson A (1995) H in rutile compounds: I. Single-crystal
neutron and X-ray diffraction study of H in
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2000s
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and ferric iron in rutile and TiO2 (II):
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MV, de Leeuw SW, Harrison NM (2004) First-principles study of H
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post-irradiation annealing of rutile (TiO2-x):
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EA (2006) Water in Nominally Anhydrous Crustal Minerals: Speciation,
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2010s
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Hydrogen and Acceptor Defects in Rutile TiO2. Physical Chemistry
Chemical Physics 12, 6817– 6825. DOI: 10.1039/b925823j
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study of OH
solubility rutile at 500-900 C, 0.5-2 GPa, and a range of oxygen
fugacities/ American Mineralogist
96, 1291-1299
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investigations at varying
temperatures on hydrous components in rutile - American
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H and Nb,Cr and V
gtrace element behavior in synthetic rutile at 600 C, 400 MPa and
possible geological application. American Mineralogist 98, 7-18.
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1000 C. Physics and Chemistry of Minerals 44, 547-522.
2020s
- Wang S, Zhang JH, Smyth JR, Zhang JF, Liu D, Zhu
X, Wang X, Ye Y (2020) Crystal Structure, Thermal Expansivity and
High-Temperature Vibrational Spectra on Natural Hydrous Rutile. Journal
of earth Science. DOI: 10.1007/s12583-020-1351-5.
- Palfey
WR, Rossman GR, Goddard WA III (2021) Structure, Energetics, and
Spectra for the Oxygen Vacancy in Rutile: Prominence of the Ti–HO–Ti Bond. Journal of Physiical Chemistry Letters, 12, 10175– 10181, DOI: 10.1021/acs.jpclett.1c02850
- Lueder
M, Tamblyn R, Hermann J (2023) A framework for quantitative
in situ evaluation of coupled substitutions between H+ and trace
elements in natural rutile. European Journal of Meralogy 35, 243–265,
- Wang
S,Su Y, Wang Q, Smyth JR, Liu D, Zhu X, iao Y, Hu Y, Ye Y (2023)
Crystal Structure, Vibrational Spectra on Trivalent-Cation-Doped Rutile
and Application in Optical Materials. The Journal of Physical Chemistry
C 127, 12160-12170. DOI: 10.1021/acs.jpcc.3c00400
- Lueder M, Tamblyn R, Rubatto D, Hermann J (2024) H2O‑rich rutile as an indicator for modern‑style cold subduction. Contributions to Mineralogy and Petrology 179:26 https://doi.org/10.1007/s00410-024-02107-2